Scale Formation of SOFC Metallic Interconnects in Coal Syngas

Planar solid oxide fuel cells (SOFCs) which can use coal syngas as the fuel and stainless steels in their construction have attracted considerable interesting, due to the high power densities and cost-effective manufacturing. However, the components of SOFCs work under a long-term, high temperature corrosive atmosphere, which places a lot of stringent requirements on the materials of the components. For interconnects, since they are simultaneously exposed to air on the cathode side and to fuel on the anode side, the materials must have good oxidation resistance, as well as other electric and mechanical properties. Although extensive research have been done to examine the oxidation behaviors of many potential interconnect materials in air, hydrogen and dual-atmosphere, little oxidation information of these materials in a coal syngas environment are available. Because the oxidation properties of materials in different media are quite different, evaluating the oxidation behavior of these potential interconnect materials in coal syngas is available.In the present work, the oxidation properties of Fe-based ferritic alloys Crofer 22 APU, E-Brite, AISI 430 and a Ni-based alloy Haynes 230 isothermally exposed in coal syngas at 800 oC for 100 hours and 500 hours were studied. Moreover, the effects of pre-oxidized coating and cladding on the oxidation properties of the materials in coal syngas at high temperatures were investigated and both of them could significantly improve the oxidation resistance

Investigation of the molecular basis for silicon biofunctionality

Despite advances in our understanding of the beneficial role of silicon in the biosphere, surprisingly little is known of the molecular mechanism by which silicon is absorbed, transported, accumulated and deposited by organisms. We used silicon-29 NMR spectroscopy to investigate the interaction of the rare amino acid 2,3-trans-3,4-cw-3,4-dihydroxy-L-proline (DHP) with aqueous silicon. Spectral data revealed the structure of three organosilicate complexes that DHP spontaneously forms with aqueous silicon at pH = 7.9, making DHP the first ever known Si-binding amino acid. Such a discovery has potential significance in accounting for silicon’s biological role in hydroxyproline-rich structural glycoproteins found in both mammals and plants. The cell wall morphology of wheat, Triticum aestivum L., grown in either -Si or +Si media was examined by optical and scanning electron microscopy. The preliminary results indicate that Si-deficiency causes swelling of the parenchyma cell walls, supporting the hypothesis that silicon may enhance cell wall integrity by cross-linking pectic polysaccharide molecules via complexation at the apiofuranose binding sites. Silicon-29 and 13C NMR spectroscopy were used to test this theory at the molecular level. Blood and urine were collected periodically from a human subject following ingestion of 29Si-enriched silicic acid and analyzed by ICP-OES and NMR spectroscopy. In addition to studying the kinetics of Si uptake and excretion, we obtained the first reliable speciation of Si-containing molecules in human biofluids, and demonstrated that mono- and disilicic acid are the predominant species

Pattern recognition-based real-time myoelectric control for anthropomorphic robotic systems : a thesis presented in partial fulfilment of the requirements for the degree of Doctor of Philosophy in Mechatronics at Massey University, Manawatū, New Zealand

All copyrighted Figures have been removed but may be accessed via their source cited in their respective captions.Advanced human-computer interaction (HCI) or human-machine interaction (HMI) aims to help humans interact with computers smartly. Biosignal-based technology is one of the most promising approaches in developing intelligent HCI systems. As a means of convenient and non-invasive biosignal-based intelligent control, myoelectric control identifies human movement intentions from electromyogram (EMG) signals recorded on muscles to realise intelligent control of robotic systems. Although the history of myoelectric control research has been more than half a century, commercial myoelectric-controlled devices are still mostly based on those early threshold-based methods. The emerging pattern recognition-based myoelectric control has remained an active research topic in laboratories because of insufficient reliability and robustness. This research focuses on pattern recognition-based myoelectric control. Up to now, most of effort in pattern recognition-based myoelectric control research has been invested in improving EMG pattern classification accuracy. However, high classification accuracy cannot directly lead to high controllability and usability for EMG-driven systems. This suggests that a complete system that is composed of relevant modules, including EMG acquisition, pattern recognition-based gesture discrimination, output equipment and its controller, is desirable and helpful as a developing and validating platform that is able to closely emulate real-world situations to promote research in myoelectric control. This research aims at investigating feasible and effective EMG signal processing and pattern recognition methods to extract useful information contained in EMG signals to establish an intelligent, compact and economical biosignal-based robotic control system. The research work includes in-depth study on existing pattern recognition-based methodologies, investigation on effective EMG signal capturing and data processing, EMG-based control system development, and anthropomorphic robotic hand design. The contributions of this research are mainly in following three aspects: Developed precision electronic surface EMG (sEMG) acquisition methods that are able to collect high quality sEMG signals. The first method was designed in a single-ended signalling manner by using monolithic instrumentation amplifiers to determine and evaluate the analog sEMG signal processing chain architecture and circuit parameters. This method was then evolved into a fully differential analog sEMG detection and collection method that uses common commercial electronic components to implement all analog sEMG amplification and filtering stages in a fully differential way. The proposed fully differential sEMG detection and collection method is capable of offering a higher signal-to-noise ratio in noisy environments than the single-ended method by making full use of inherent common-mode noise rejection capability of balanced signalling. To the best of my knowledge, the literature study has not found similar methods that implement the entire analog sEMG amplification and filtering chain in a fully differential way by using common commercial electronic components. Investigated and developed a reliable EMG pattern recognition-based real-time gesture discrimination approach. Necessary functional modules for real-time gesture discrimination were identified and implemented using appropriate algorithms. Special attention was paid to the investigation and comparison of representative features and classifiers for improving accuracy and robustness. A novel EMG feature set was proposed to improve the performance of EMG pattern recognition. Designed an anthropomorphic robotic hand construction methodology for myoelectric control validation on a physical platform similar to in real-world situations. The natural anatomical structure of the human hand was imitated to kinematically model the robotic hand. The proposed robotic hand is a highly underactuated mechanism, featuring 14 degrees of freedom and three degrees of actuation. This research carried out an in-depth investigation into EMG data acquisition and EMG signal pattern recognition. A series of experiments were conducted in EMG signal processing and system development. The final myoelectric-controlled robotic hand system and the system testing confirmed the effectiveness of the proposed methods for surface EMG acquisition and human hand gesture discrimination. To verify and demonstrate the proposed myoelectric control system, real-time tests were conducted onto the anthropomorphic prototype robotic hand. Currently, the system is able to identify five patterns in real time, including hand open, hand close, wrist flexion, wrist extension and the rest state. With more motion patterns added in, this system has the potential to identify more hand movements. The research has generated a few journal and international conference publications

Islanding Detection for Microgrid Based on Frequency Tracking Using Extended Kalman Filter Algorithm

Islanding detection is essential for secure and reliable operation of microgrids. Considering the relationship between the power generation and the load in microgrids, frequency may vary with time when islanding occurs. As a common approach, frequency measurement is widely used to detect islanding condition. In this paper, a novel frequency calculation algorithm based on extended Kalman filter was proposed to track dynamic frequency of the microgrid. Taylor series expansion was introduced to solve nonlinear state equations. In addition, a typical microgrid model was built using MATLAB/SIMULINK. Simulation results demonstrated that the proposed algorithm achieved great stability and strong robustness in of tracking dynamic frequency

Effects of in ovo feeding of chlorogenic acid on antioxidant capacity of postnatal broilers

In this study, chlorogenic acid (CGA) was injected into the amniotic cavity of chicken embryos to study the effects of in ovo feeding of CGA on the antioxidant capacity of postnatal broilers. On the 17th day of embryonic age, a total of 300 healthy broiler fertile eggs with similar weights were randomly subjected to five groups as follows; in ovo injection with 0.5 ml CGA at 4 mg/egg (4CGA) or 7 mg/egg (7CGA) or 10 mg/egg (10CGA), or sham-injection with saline (positive control, PC) or no injection (negative control, NC). Each group had six replicates of ten embryos. Six healthy chicks with similar body weights hatched from each replicate were selected and reared until heat stress treatment (35°C ± 1°C, 8 h/d) at 28–42 days of age. The results showed that there was no significant difference in the hatching rate between the groups (p > 0.05). After heat stress treatment, 4CGA group showed an improved intestinal morphology which was demonstrated by a higher villus height in the duodenum and a higher villus height/crypt depth ratio in the jejunum, compared with the NC group (p < 0.05). The antioxidant capacity of chickens was improved by in ovo feeding of CGA since 4CGA decreased the plasma content of malondialdehyde (MDA) (p < 0.05), whereas, it increased the superoxide dismutase (SOD), glutathione peroxidase (GPX), and catalase (CAT) activities compared with NC group (p < 0.05). Also, the MDA content of the different injection groups had a quadratic effect, with the 4CGA group having the lowest MDA content (Pquadratic < 0.05). In the duodenum, 4CGA injection significantly increased the mRNA expressions of nuclear factor erythroid 2-related factor 2 (Nrf2), heme oxygenase 1 (H O -1), glutathione synthetase (GSS), and SOD1 compared to the NC and PC groups (p < 0.05). The mRNA expressions of glutathione reductase (GSR) and GPX7 were significantly increased in all CGA-treated groups compared with the PC group (p < 0.05), while the mRNA expression of CAT was significantly increased by 4CGA group than the NC group (p < 0.05). The mRNA expressions of epigenetic-related genes, ten eleven translocation 1 and 2 (Tet1 and Tet2), and DNA-methyltransferase 3 alpha (DNMT3A) in the duodenum of 4CGA injected group was significantly increased compared with the NC and PC groups (p < 0.05). The mRNA expressions of Nrf2, SOD1, and Tet2 showed a significant quadratic effects with the 4CGA group having the highest expression (Pquadratic < 0.05). In conclusion, in ovo feeding of CGA alleviated heat stress-induced intestinal oxidative damage. Injection with CGA of 4 mg/egg is considered most effective due to its actions in improving intestinal antioxidant capacity, especially in the duodenum. The antioxidant effects of in ovo CGA on postnatal heat-stressed broilers may be related to its regulation of epigenetic mechanisms. Thus, this study provides technical knowledge to support the in ovo feeding of CGA to alleviate oxidative stress in postnatal heat-stressed broilers

Exploring personalised autonomous vehicles to influence user trust

Trust is a major determinant of acceptance of an autonomous vehicle (AV), and a lack of appropriate trust could prevent drivers and society in general from taking advantage of such technology. This paper makes a new attempt to explore the effects of personalised AVs as a novel approach to the cognitive underpinnings of drivers’ trust in AVs. The personalised AV system is able to identify the driving behaviours of users and thus adapt the driving style of the AV accordingly. A prototype of a personalised AV was designed and evaluated in a lab-based experimental study of 36 human drivers, which investigated the impact of the personalised AV on user trust when compared with manual human driving and non-personalised AVs. The findings show that a personalised AV appears to be significantly more reliable through accepting and understanding each driver’s behaviour, which could thereby increase a user’s willingness to trust the system. Furthermore, a personalised AV brings a sense of familiarity by making the system more recognisable and easier for users to estimate the quality of the automated system. Personalisation parameters were also explored and discussed to support the design of AV systems to be more socially acceptable and trustworthy

PHLPP Negatively Regulates Cell Motility Through Inhibition of Akt Activity and Integrin Expression in Pancreatic Cancer Cells

Pancreatic adenocarcinoma is currently the fourth leading cause for cancer-related mortality. Malignant progression of pancreatic cancer depends not only on rapid proliferation of tumor cells but also on increased cell motility. In this study, we showed that increased PHLPP expression significantly reduced the rate of migration in pancreatic ductal adenocarcinoma (PDAC) cells whereas knockdown of PHLPP had the opposite effect. In addition, cell motility at the individual cell level was negatively regulated by PHLPP as determined using time-lapse imaging. Interestingly, the expression of β1 and β4 integrin proteins were decreased in PHLPP overexpressing cells and increased in PHLPP knockdown cells whereas the mRNA levels of integrin were not altered by changes in PHLPP expression. In determining the molecular mechanism underlying PHLPP-mediated regulation of integrin expression, we found that inhibition of lysosome activity rescued integrin expression in PHLPP overexpressing cells, thus suggesting that PHLPP negatively controls cell motility by inhibiting Akt activity to promote lysosome-dependent degradation of integrins. Functionally, the increased cell migration observed in PHLPP knockdown cells was effectively blocked by the neutralizing antibodies against β1 or β4 integrin. Taken together, our study identified a tumor suppressor role of PHLPP in suppressing cell motility by negatively regulating integrin expression in pancreatic cancer cells

Cross-Linked ZnO Nanowalls Immobilized onto Bamboo Surface and Their Use as Recyclable Photocatalysts

A novel recyclable photocatalyst was fabricated by hydrothermal method to immobilize the cross-linked ZnO nanowalls on the bamboo surface. The resultant samples were characterized by using scanning electron microscopy (SEM), X-ray diffraction (XRD), energy dispersive spectroscopy (EDS), and Fourier transformation infrared (FTIR) techniques. FTIR spectra demonstrated that the cross-linked wurtzite ZnO nanowalls and bamboo surface were interconnected with each other by hydrogen bonds. Meanwhile, the cross-linked ZnO nanowalls modified bamboo (CZNB) presented a superior photocatalytic ability and could be recycled at least 3 times with a photocatalytic efficiency up to 70%. The current research provides a new opportunity for the development of a portable and recycled biomass-based photocatalysts which can be an efficiently degraded pollutant solution and reused several times

Tibetan sheep have a high capacity to absorb and to regulate metabolism of SCFA in the rumen epithelium to adapt to low energy intake

The nutritional intake of Tibetan sheep on the harsh Qinghai-Tibetan Plateau is often under maintenance requirements, especially during the long, cold winter. However, they have adapted well and even thrive under these conditions. The aim of the present study was to gain insight into how the rumen epithelium of Tibetan sheep has adapted to the consumption of low-energy-level diets. For this purpose, we compared Tibetan and small-tailed Han sheep (n 24 of each breed, all wethers and 1 center dot 5 years of age), which were divided randomly into one of four groups and offered ad libitum diets of different digestible energy (DE) densities: 8 center dot 21, 9 center dot 33, 10 center dot 45 and 11 center dot 57 MJ DE/kg DM. The Tibetan sheep had higher rumen concentrations of total SCFA, acetate, butyrate and iso-acids but lower concentrations of propionate than small-tailed Han sheep. The Tibetan sheep had higher absorption capability of SCFA due to the greater absorption surface area and higher mRNA expression of the SCFA absorption relative genes than small-tailed Han sheep. For the metabolism of SCFA in the rumen epithelium, the small-tailed Han sheep showed higher utilisation of the ketogenesis pathway than Tibetan sheep; however, Tibetan sheep had greater regulation capacity in SCFA metabolism pathways. These differences between breeds allowed the Tibetan sheep to have greater capability of absorbing SCFA and better capacity to regulate the metabolism of SCFA, which would allow them to cope with low energy intake better than small-tailed Han sheep